Higher Density Multi-Component and Serial Packages

ABSTRACT

A high density multi-component package is provided. The package has at least two electronic components wherein each electronic component comprises a first external termination and a second external termination. At least one first adhesive is between adjacent first external terminations of adjacent electronic components. At least one second adhesive is between the adjacent electronic component and at least two adjacent electronic components are connected serially. The first adhesive and second adhesive are independently selected from a high temperature conductive adhesive and a high temperature insulating adhesive

FIELD OF THE INVENTION

The present invention is related to a high-density package of electronic components, and a method of making the package, wherein increased functionality can be achieved in a limited footprint. More specifically, the present invention is specific to a high-density package comprising combinations of high temperature conductive adhesive and high temperature insulating adhesive between adjacent electronic components which allow for serial connectivity of a variety of electronic components.

BACKGROUND

There is an on-going need in electronics to provide increased functionality in increasingly smaller devices. This desire, referred to as miniaturization, has dominated research efforts associated with components, mounting techniques and the like. While most of the effort has been focused on decreasing the footprint of electronic components on a circuit board more recent efforts have focused on stacking components thereby occupying the space above and below the board instead of occupying surface area of the board.

Stacked multi-layer ceramic capacitors (MLCC) are described in commonly assigned U.S. Pat. No. 9,472,342, to McConnell et al., which is incorporated herein by reference, wherein leadless multi-layer ceramic capacitors are formed in stacks where two or more MLCC's are bonded together by their terminations using transient liquid phase sintering (TLPS) adhesives. The resulting stack can be surface mounted by techniques known in the art, such as soldering, since the TLPS does not reflow at the soldering temperature.

While advantageous, the leadless stacks provide capacitors in electrical parallel only and therefore the applications are somewhat limited. There are many applications requiring electronic components serially connected. Serially connected components can be achieved by bonding the terminals of the respective components end-to-end, rather than in a stack, however this increases the space required for mounting which is contrary to the overwhelming desire for miniaturization.

There is an ongoing necessity for a package comprising multiple components, which can be serially connected, while minimizing the footprint of the package on the circuit board. Provided herein is an improved package for multiple components, preferably including at least one MLCC, wherein at least some of the electronic components in the package are serially connected.

SUMMARY OF THE INVENTION

The present invention is related to high density multi-component packages.

More specifically, the present invention is related to high density multi-component packages which allow for serial or parallel connectivity of different components in the package.

A particular feature of the invention is the ability to mount a high density package on a circuit board either vertically or horizontally.

These and other embodiments, as will be realized, are provided in a high density multi-component package. The package has at least two electronic components wherein each electronic component comprises a first external termination and a second external termination. At least one first adhesive is between adjacent first external terminations of adjacent electronic components. At least one second adhesive is between the adjacent electronic component and at least two adjacent electronic components are connected serially. The first adhesive and second adhesive are independently selected from a high temperature conductive adhesive and a high temperature insulating adhesive

Yet another embodiment is provided in an electronic circuit. The electronic circuit has a high density multi-component package wherein the package comprises at least two electronic components wherein each electronic component comprises a first external termination and a second external termination, at least one first adhesive between adjacent first external terminations, at least one second adhesive between adjacent electronic components and wherein at least two adjacent electronic components are connected serially. The first adhesive and second adhesive are independently selected from a high temperature conductive adhesive and a high temperature insulating adhesive. The electronic circuit also comprises a circuit board comprising traces wherein at least one trace is an active trace and at least one trace of said traces is a mechanical trace. At least one first external termination of a first electronic component is in electrical contact with one active trace. At least one second external termination of a second electronic component is in electrical contact with a mechanical trace.

Yet another embodiment is provided in a method for forming a high density multi-component package. The method includes:

providing at least two electronic components wherein each electronic component comprises a first external termination and a second external termination; forming a stack of adjacent electronic components; attaching adjacent first external terminations with a first adhesive there between; attaching adjacent electronic components with a second adhesive there between; wherein the first adhesive and second adhesive are independently selected from the group consisting of a high temperature conductive adhesive and a high temperature insulating adhesive; and wherein the adjacent electronic components are connected serially.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 is a schematic side view representation of an embodiment of the invention.

FIG. 2 is a schematic side view representation of an embodiment of the invention.

FIG. 3 is a schematic cross-sectional side view representation of an embodiment on the invention.

FIG. 4 is a schematic cross-sectional side view representation of an embodiment on the invention.

FIG. 5 is a schematic top view representation of an embodiment of the invention.

FIG. 6 is a schematic top view representation of an embodiment of the invention.

FIG. 7 is an electrical schematic representation of an embodiment of the invention.

FIG. 8 is an electrical schematic representation of an embodiment of the invention.

FIG. 9 is a schematic top view representation of an embodiment of the invention.

FIG. 10 is a schematic side view representation of an embodiment of the invention.

FIG. 11 is an electrical schematic representation of an embodiment of the invention.

FIG. 12 is an electrical schematic representation of an embodiment of the invention.

FIG. 13 is schematic side view representation of an embodiment of the invention.

FIG. 14 is schematic side view representation of an embodiment of the invention.

FIG. 15 is an electrical schematic representation of an embodiment of the invention.

FIG. 16 is an electrical schematic representation of an embodiment of the invention.

FIG. 17 is an electrical schematic representation of an embodiment of the invention.

FIG. 18 is a schematic side view representation of an embodiment on the invention.

FIG. 19 is a schematic side view representation of an embodiment on the invention.

FIG. 20 is a schematic cross-sectional side view representation of an embodiment on the invention.

FIG. 21 is a schematic cross-sectional side view representation of an embodiment on the invention.

FIG. 22 is an electrical schematic representation of an embodiment of the invention.

FIG. 23 schematic cross-sectional top view representation of an embodiment on the invention.

FIGS. 24 and 25 are electrical schematic representations of embodiments of the invention.

FIG. 26 is an electrical schematic representation of an embodiment of the invention.

FIG. 27 schematic cross-sectional top view representation of an embodiment on the invention.

FIG. 28 is a schematic cross-sectional side view representation of an embodiment on the invention.

FIG. 29 is a schematic cross-sectional side view representation of an embodiment on the invention.

DESCRIPTION

The present invention is related to a high density multi-component package of electronic components wherein at least some of the electronic components are serially connected and the package minimizes surface area required on the circuit board. More specifically, the present invention is related to a stack of electronic components comprising a combination of high temperature conductive adhesives (HTCA) and high temperature insulating adhesives (HTIA) between adjacent external terminations of adjacent electronic components or between adjacent electronic components.

The high density multi-component package of the present invention comprises a combination of HTCA and HTIA between adjacent electronic components thereby providing for a serial configuration. Previous art requires indirect connections via addition of interposers and HTCA materials between components or linking of components via connections via traces in the control board strata. In the present invention the HTCA provides for an electrical connection between terminals of adjacent components within the stack of electronic components. The HTIA provides a mechanical bond and electrical insulation between adjacent components. The combination of HTCA and HTIA allows components to be arranged in a higher density package with serial and parallel connectivity. This compaction can be beneficial in either the vertical or horizontal mounting configuration. In one embodiment, the package of electronic components can be surface mounted with the end terminals of the outermost components electrically connected to the circuit. The high density multi-component package can be used to form high density packages containing mixed electronic components and provides the flexibility to connect the electronic component in electrical series as well as in electrical parallel thereby enabling high density packages of multifunctional components with a variety of electronic configurations. The HTCA and HTIA can be bonded in the same process or separately. Furthermore, the components can be formed into a bonded stack and the stack mounted to a circuit board or the circuit board mounting and stack formation can occur in concert.

The invention will be described with reference to the figures forming an integral, non-limiting, component of the disclosure. Throughout the various figures similar elements will be numbered accordingly.

An embodiment of the invention will be described with reference to FIG. 1 wherein a high density multi-component package, 30, is illustrated in schematic side view. In FIG. 1, four electronic components are illustrated for the purposes of discussion without limit thereto. Each electronic component is arbitrarily numbered for the purposes of illustration and discussion only. In FIG. 1, HTCA's, 10, and HTIA's, 11, are between adjacent external terminations of adjacent electronic components. Each electronic component has one external termination, 32, in either electrical contact with and adjacent external termination through a HTCA, 10, or physically attached with a insulating bond through a HTIA, 11, which is preferably between adjacent external terminations. In FIG. 1 an electronic path is formed beginning arbitrarily at external termination, 32 ¹, of electronic component 1, and ending with external termination, 32 ⁸, of electronic component 4. The four electronic components are therefore all serially connected. While four electronic components are a sufficient number to illustrate the invention it is to be understood that the invention can be extended from two components to any number of electronic components and a large variety of variations as will be realized. It is preferable that the number of components is at least two to no more than 100.

An embodiment of the invention will be described with reference to FIG. 2 wherein a high density multi-component package vertically mounted to a substrate, 36, is illustrated in schematic side view. Active circuit traces, 38, on the substrate, 36, are in functional electronic connection with external terminations, 32 ¹ and 32 ⁸. External termination, 32 ¹, is directly attached to active circuit trace 38 ¹ by an interconnect, 42, which may be the same as the HTCA forming the interconnect between adjacent external terminations or it may be different. A connector, 44, is in electrical contact with external termination 32 ⁸ and active trace 38 ² wherein the active traces, 38, are integral to the electronic circuit of a device, 30. The connector may be an electrical connection and otherwise provide no further function or the connector may be a functional connection such as an electrical component. Particularly preferred connectors include a resistor, a fuse, an inductor or a flexible circuit. A mechanical trace, 40, provides mechanical stability and is directly attached to external termination 32 ² by an interconnect, 42.

An embodiment of the invention will be described with reference to FIGS. 3 and 4 wherein a flex circuit is utilized as the connector. With reference to FIG. 3 a flex circuit connector, 144, shown in cross-sectional schematic view, comprises a flexible substrate, 160. An optional but preferred mechanical pad, 20, provides for mechanical attachment to an external termination, 32 ⁶ of FIG. 4, or between the body of the electronic components, for mechanical robustness. A pair of conducting pads, 18, are in electrical connection with vias, 14, which are in electrical contact with a trace, 146. A conducting pad is in electrical contact with an external termination, 32 ⁵, and a conducting pad is in electrical contact with a circuit trace, 38 ².

An embodiment of the invention will be described with reference to FIG. 5 wherein a high density multi-component package horizontally mounted to a circuit board, 36, is illustrated in schematic top view. In FIG. 5, each external termination, 32, is attached to a trace of the circuit board with external terminations 32 ¹ and 32 ⁸ attached to active traces 38 ¹ and 38 ², respectively, which are in electrical contact with the circuit traces, 46. The remaining external terminations are attached to mechanical traces, 40, preferably through a solder pad, 43, by an interconnect which is not shown. In FIG. 5 the electronic components are all serially connected. In FIG. 5 the HTIA is optional as the electronic components are mechanically secured to the circuit board. The HTIA is still preferable as it provides mechanical stability and thus allows for the manufacture of a stack of electronic components prior to and independent of the board mounting process. This also facilitates part testing prior to board assembly.

An embodiment of the invention will be described with reference to FIG. 6 wherein a high density multi-component package is illustrated in schematic top view mounted to a substrate, 36. In FIG. 6 electronic components 1 and 4 are mounted as illustrated and described relative to FIG. 5. Electronic components 2 and 3 have a HTCA, 10, directly there between and therefore the electronic components 2 and 3 are in electrical parallel. A generic electrical schematic diagram is illustrated in FIG. 7 wherein electronic components 2 and 3 are in electrical parallel between serially connected electronic components 1 and 4. An electrical schematic diagram is provided in FIG. 8 wherein electrical component 1 is an inductor, electrical components 2 and 3 are MLCC's and electrical component 4 is a fuse thereby providing a fused inductor capacitor high density component.

An embodiment of the invention will be described with reference to FIGS. 9 and 10 wherein a portion of an electronic circuit of a device is illustrated in top schematic view in FIG. 9 and side schematic view in FIG. 10. For the purposes of discussion, a series of pads, 58, are numbered sequentially. Traces, 54, connecting adjacent pads are designated by the pads being electrically connected. Trace 54 ²³, for example, provides electrical conductivity between pads 58 ² and 58 ³. HTIA's, 11, are between adjacent electronic components wherein pads 58 ¹ and 58 ⁸ provide connectivity to the circuit by traces, 56. A secondary electrical component, 5, electrically mounted in parallel with electrical components 2 and 3 at the external termination provides a combination of serial and parallel electrical connections and component 5 does not increase the surface area of the circuit board, 36, occupied by the package, 111. A secondary electrical component is an electrical component which is peripheral to the stack but electrically connected thereto thus adding to the circuits capabilities without increasing its footprint. While demonstrated with five electrical components the number and arrangement of electrical components is not limited herein.

A representative circuit diagram for the package illustrated in FIGS. 9 and 10 is provided in FIG. 11 wherein electronic components 1, 2, 3 and 4 are electrically serially connected and component 5 is electrically parallel to components 2 and 3. An exemplary embodiment is illustrated in FIG. 12 wherein electronic component 1 is an inductor, electronic components 2 and 3 are MLCC's, electronic component 5 is a resistor and electronic component 4 is a fuse.

An embodiment of the invention will be described with reference to FIG. 13 wherein a high density multi-component package mounted to a substrate, 36, is illustrated in partial cross-sectional schematic view. In FIG. 13, the electronic components are in parallel adjacent stacks with a secondary electronic component, P, spanning across electronic components N and M. In one embodiment, electronic component P could be an interposer or a flexible circuit with two active pads and a trace there between for electrical connectivity between the active pads. As illustrated, without limit thereto, pads, 62, are active pads in electrical communication with circuit traces, not shown, and pads, 60, are mechanical pads which are not otherwise electrically connected to the circuit. An over-molding, 64, may be included to prevent surface arcing, to create a barrier to moisture penetration or to facilitate mechanical placement.

In a further embodiment of the invention by increasing the number of active connections to the circuit board it is possible to achieve an electrical filter within a high density component package. Pi, T, and LC filters are widely used in either feed through or surface mount configurations but there is a desire to continue to miniaturize these packages and provide a high-density surface mountable solution. An example of a Pi-filter package is shown in FIG. 14 wherein electronic component 2 is an inductor and electronic components 1 and 3 are MLCC's. The input and output of the inductor is connected through an MLCC to ground traces, 51, thereby providing a Pi filter with an electrical schematic diagram illustrated in FIG. 15. Only the active circuit traces are shown in FIG. 14 and other non-active pads may be added for a mechanical bond for increased mechanical stability. An electronic schematic diagram for an “LC” filter is illustrated in FIG. 16 and a “T” filter is illustrated in FIG. 17.

In the case where the component to be attached has a face-down termination an active interposer with a reorientation via can be used as shown in FIG. 18 wherein a conducting pad, 18, is electrically connected by a via, 14, to a conducting pad, 72. When used as depicted in FIG. 19 one of the faced down terminals is connected to the circuit and the other to one terminal of the next component, 76, by connection to the re-orientation via to form a serial connection. Each pad, 74, independently represent either mechanical pads or conducting pads as necessary thereby allowing for flexibility in the design of the electronic components and the functionality of the high density multi-component package.

An embodiment of the invention will be described with reference to FIG. 20. In FIG. 20 a multiplicity of components, 1-8, are illustrated with adjacent components in one plane, 1 and 2 or 3 and 4 or 5 and 6 or 7 and 8 for example, are serially connected through common electrical attachment by HTCA, 10. Adjacent components, such as 1 and 4, are in mechanical contact with HTIA, 11, there between. By providing multiple pads and combinations of HTCA and HTIA multiple arrangements of components can be provided in a limited space.

An embodiment of the invention will be described with reference to FIG. 21. In FIG. 21, a combination of HTCA and HTIA provides the flexibility to form serial and parallel electrical connections. Inter-stack HTCA, 10, provides electrical conductivity between adjacent stacks, S₁ and S₂ of components wherein, for the purposes of illustration, stack S₁ comprises components 1, 2 and 3 and stack S₂ comprises components 4, 5 and 6. For the purposes of illustration adjacent components 3 and 6 and adjacent components 2 and 5 provide a package with two groups of components 2-5 and 3-6 in electrical series with each set in electrical series with component 1 and 4 as represented schematically in FIG. 22. In FIG. 21 the package is in electrical contact with active circuit traces, 38, on a circuit board, 36, with mechanical circuit traces, 40, provided for mechanical support. Alternatively, a mechanical circuit trace, 40 ¹ for example, may be an active circuit thereby allowing for the use of a portion of the stack, only component 1 for example, with the functionality of component 1, in this illustration, to be isolated between traces 38 ¹ and 40 ¹. This allows for testing of individual components within the package.

An embodiment of the invention will be described with reference to FIG. 23 wherein a package is provided which allows multi-terminal components to be connected to the circuit through the use of HTCA and HTIA. In FIG. 23 three components are illustrated, without limit thereto, with HTCA between adjacent components and with each external termination of each component in electrical contact with a circuit trace. Depending on the desired functionality of the package some circuit traces, 151, can be active and some can be mechanical. By way of example, traces 151 ^(A), 151 ^(C) and 151 ^(B) can be active to provide the schematic of FIG. 24 which could provide the T-filter of FIG. 17 when components 1 and 3 are inductors and component 2 is a capacitor. Alternatively, traces 151A, 151B and 151E could be utilized to provide the schematic of FIG. 25 which could provide the LC, or L filter of FIG. 17 when component 1 is an inductor and component 2 is a capacitor. By the use of alternate arrangements of HTCA and HTIA circuit traces 151A, 151B, 151C and 151F could be utilized to provide the schematic of FIG. 26 which could provide the Pi filter of FIG. 15 if components 1 and 3 are capacitors and component 2 is an inductor. A single package can provide multiple functions. It would be understood that the number of components can be quite large and therefore the functionality can be essentially limitless.

An embodiment of the invention is illustrated in schematic cross-sectional view in FIG. 27. In FIG. 27 two electronic components are illustrated with the understanding that the two electronic components could be a portion of a stack of electronic components. In FIG. 27 external terminations 32 ¹ and 32 ² are in electrical contact through a HTCA, 10, as described elsewhere herein. External terminations 32 ³ and 32 ⁴ are not in electrical contact having instead a spacer, 9, there between wherein the spacer can be an air gap or a non-conductive material wherein the non-conductive material may be a HTIA. A secondary adhesive, 12, which is preferably not conductive, adheres the body of the adjacent electronic components for stability purposes. The adhesive may be in contact with one external termination of one electronic component and the body of the adjacent electronic component. For the purposes of the instant invention a secondary adhesive is an adhesive which is in mechanical contact with at least one body of at least one electronic component and may otherwise be in mechanical contact with a body of a second electronic component, an external termination of a second electronic component or a solder pad.

An embodiment of the invention is illustrated in schematic side view in FIG. 28 wherein two stacks of electronic components, represented by 1-8 without limit thereto, is illustrated mounted vertically to a substrate, 36. A spacer, 17, is provided which functions as an insulator between adjacent external terminations of adjacent electronic components. As would be realized a stack as represented in FIG. 28 could be mounted horizontally, as in FIG. 5, and alternate arrangements of HTCA, HTIA and spacers could be employed thereby allowing for combinations of serial and parallel electrical connections as set forth elsewhere herein.

An embodiment of the invention is illustrated in schematic side view in FIG. 29. In FIG. 29 a HTIA, 11, is between adjacent electronic components thereby allowing for serial connectivity of the stacked electronic component. Adjacent external terminations are in electrical connection by HTCA's, 10, as described elsewhere herein. As would be realized a stack as represented in FIG. 29 could be mounted horizontally, as in FIG. 5, and alternate arrangements of HTCA and HTIA could be employed, with the further inclusion of spacers, thereby allowing for combinations of serial and parallel electrical connections as set forth elsewhere herein.

A particular advantage of the instant invention is an improvement in inductance. A high density multi-component stack mounting in a horizontal direction, as in FIG. 5, reduces stray inductance as the path length between the electronic component and circuit board is reduced, and therefore so is the Equivalent Series Inductance (ESL). Furthermore, when mounted in the horizontal direction the Equivalent Series Resistance (ESR) is also lowered since this results in shorter connectivity pathways' to the components compared to the vertical mounting direction.

Each electronic component is preferably independently selected from the group consisting of capacitor, resistor, varistor, inductor, diode, fuse, overvoltage discharge device, sensor, switch, electrostatic discharge suppressor, semiconductor and integrated circuit. The diode may be a light emitting diode. More preferably the electronic elements are selected from the group consisting of capacitor, resistor, varistor, inductor, diode, fuse, overvoltage discharge device, sensor, switch and electrostatic discharge suppressor. It is preferred that the capacitor is an MLCC and more preferably at least one of the electronic components is an MLCC.

The external terminations of the electronic components are not particularly limited herein with the proviso that they can be attached to a pad, either active or mechanical by a HTCA or HTIA. TLPS is the preferred HTCA interconnect between the external termination of the electronic component and pad. The external termination may be one component of TLPS, as will be more fully described herein, wherein additional components of the TLPS are either inserted between the external termination to be bound or is integral to the surface to which the external termination is to be bound. The TLPS materials are compatible with surface finishes containing silver, tin, gold, copper, platinum, palladium, nickel, or combinations thereof, either as lead frame finishes, component connections or inner electrodes to form an electronically conductive metallurgical bond between two surfaces.

Transient liquid phase sintering (TLPS) adhesives form a termination to an electronic element or attach external terminations to a surface such as a solder pad or adjacent external terminations thereby functioning as an interconnect. TLPS terminations have the advantage of being able to accommodate different surface finishes as well as electronic elements of differing lengths. Furthermore, since no solder balls are formed electronic elements can be stacked on top of each other with only TLPS there between and without the gaps normally required for cleaning as with solder attachment technology. TLPS can be directly bonded with the inner electrodes of the electronic component, when the electronic element is an MLCC, and the termination can be formed at low temperature. In an embodiment, higher density terminations can be prepared by using a thermo-compression process thereby forming improved external lead attachment bonds.

Solders are alloys which do not undergo a change in composition after the first reflow. Solders have only one melting point and can be re-melted an indefinite number of times. A common solder is 60% Sn40% Pb. Solders have been the materials of choice in electronics to provide the mechanical and electrical interconnects between electronic elements and circuit boards or substrates. Solders are very well suited for mass volume production assembly processes. The physical properties of solder can be altered simply by changing the ratios or the metals used to create a solder alloy. When solder is referenced herein it will imply an alloy of at least two metals that can be re-melted multiple times at nearly the same temperature.

Transient liquid phase sintering (TLPS) bonds are distinguishable from solders. TLPS materials are mixtures of two or more metals or metal alloys prior to exposure to elevated temperatures thereby distinguishing the thermal history of the material. TLPS materials exhibit a low melting point prior to exposure to elevated temperatures, and a higher melting point following exposure to these temperatures. The initial melting point is the result of the low temperature metal or an alloy of two low temperature metals. The second melting temperature is that of the intermetallic formed when the low temperature metal or alloy forms a new alloy with a high temperature melting point metal thereby creating an intermetallic having a higher melting point. This is particularly advantageous when used as the HTCA in the high-density package since the TLPS melting point can be easily selected to be higher than that of the interconnects used in the circuit board assembly. TLPS materials form a metallurgical bond between the metal surfaces to be joined. Unlike tin/lead or lead (Pb) free solders, the TLPS adhesives do not spread as they form the intermetallic joint. Rework of the TLPS system is very difficult due to the high secondary reflow temperatures. Transient Liquid Phase Sintering is the terminology given to a process to describe the resulting metallurgical condition when two or more TLPS compatible materials are brought in contact with one another and raised to a temperature sufficient to melt the lower temperature metal. To create a TLPS process or interconnect at least one of those metals is from a family of metals having a low melting point, such as tin (Sn) or indium (In), and the second metal is from a family having high melting points, such as copper (Cu) or silver (Ag). When Sn and Cu are brought together, and the temperature elevated, the Sn and Cu form CuSn intermetallics and the resulting melting point is higher than the melting point of the metal having a low melting point. In the case of In and Ag, when sufficient heat is applied to the In to cause it to melt it actually diffuses into the Ag creating a solid solution which in turn has a higher melting point than the In itself. TLPS will be used to generically reference the process and the TLPS compatible materials used to create a metallurgical bond between two or more TLPS compatible metals. TLPS provides an electrical and mechanical interconnect that can be formed at a relatively low temperature (<300° C.) and having a secondary re-melt temperature >600° C. These temperatures are determined by the different combination of TLPS compatible metals. TLPS will be used to generically pertain to the process and materials used to create a TLPS metallurgical bond or interconnect. The rate of diffusion or sintering is a time temperature function and is different for the different combinations of metals. The result is a solid solution having a new melt temperature approaching that of the high temperature melting metal.

The TLPS technology is particularly suited to providing both a mechanical and electrical conductive metallurgical bond between two mating surfaces preferably that are relatively flat. The metals typically used for the TLPS process are selected from two metal families. One consists of low melting temperature metals such as indium, tin, lead, antimony, bismuth, cadmium, zinc, gallium, tellurium, mercury, thallium, selenium, or polonium and a second family consisting of high temperature melting metals such as silver, copper, aluminum, gold, platinum, palladium, beryllium, rhodium, nickel, cobalt, iron and molybdenum to create a diffused solid solution.

It is highly desirable to use a flux free process to eliminate any potential voids within the joint. Since TLPS is a sintering based process, the bond line is uniform and void free. Fluxes, which are necessary with solders, get entrapped in the joint and are subsequently burned out leaving a void. In the case with the semi-conductor industry, and specifically with die attach processes, these voids can create hot spots within the integrated circuit (I/C) which can lead to premature failure and reliability issues. TLPS addresses this issue since TLPS is a sintering process and free of fluxes. When the two metals are mated together and heat is applied, the lower melting metal diffuses into the higher melting metal to create a solid solution across the mating surface area. To create a solid uniform bond line it is mandatory that the mating surfaces be flat and coplanar to insure intimate contact across the entire mating surface. The required flatness of the mating surfaces also limits the application of this technology because there are many surfaces that are not sufficiently planar to yield a good joint.

The use of TLPS in paste form allows uneven surfaces to be joined. More specifically, the use of TLPS in paste form allows two irregular shaped surfaces to be joined with no intimate, or continuous, line of contact. A TLPS compatible metal particle core combined with a liquid carrier material to form a paste can be applied between two non-planar non-uniform surfaces having mixed surface preparation technologies such as plating, sintered thick film, and or plated sintered thick film and then heating to the melting temperature of the metal having the lowest melting point and holding that temperature for a sufficient amount of time to form a joint. A single metal particle core eliminates the need for multiple metals in a paste thus making the ratios of metals a non-issue. It is also possible to create a single particle by using silver, a metal having a high melting point of approximately 960° C. as a core particle, and then coating that particle with a metal shell having a low temperature metal such as indium having a melting point of 157° C.

A two-step reflow can also be used with the transient liquid phase sintering process wherein in the first step an electrically conductive metallurgical bond is formed at low temperature using a relatively short time cycle, in the range of 5 seconds to 5 minutes, and low temperature, in the range of 180° C. to 280° C., depending on the metals being used in the TLPS alloying process. In the second step the part is subjected to an isothermal aging process using a temperature range of 200° C. to 300° C. for a longer duration such as, but not limited to, 5 minutes to 60 minutes. The shorter times required to form the initial bond are well suited for an automated process. In another method a single step process can be used wherein the TLPS forms a terminal, or conductive metallurgical bond, between the external leads and electronic element(s) at temperatures of, for example, 250° C. to 325° C. for a duration of, for example, 10 seconds to 30 seconds. Lower temperatures, such as 175° C. to 210° C., can be used for a longer duration, such as 10 to 30 minutes. This is particularly useful when the electronic component itself is sensitive to temperature.

Indium powder mixed with a flux and solvent to form a paste can be applied to produce a TLPS metallurgical bond between two coupons having a base metal of copper overplated with Ni and then overplated with about 5 microns (200 μinches) of silver. The samples can be prepared by dispensing the indium paste onto a coupon having the plated surfaces as mentioned and then placing two coupons in contact with one another and heating to 150° C. for 5 seconds, followed by increasing the temperature to about 320° C. for about 60 seconds. The joint strength of the sample thus prepared can exhibit a pull weight in the range of 85-94 pounds equating to shear stress of 4,177 psi and a pull peel weight in the range of 5-9 pounds with an average of 7 pounds can be achieved. These results are comparable to results for SnPb solders having shear strengths of approximately 3000 psi and pull peel strengths in the 7-10 pound range. One major difference is that the Agln joint can withstand secondary melt temperatures exceeding 600° C. These results indicate that the In paste used to bond two silver plated coupons is at least equivalent if not stronger than current solder SnPb solders but also has a much higher secondary melt temperature thus yielding a material suitable for high temperature interconnect applications and also being lead free. The TLPS paste or preform may have inert fillers therein to serve two purposes. One purpose is to minimize the cost due to expensive metals and the second purpose is to make direct electrical and metallurgical bonds directly to the non-terminated ends of the electronic element and exposed internal electrodes. The cost can be reduced, particularly, when a gap is to be filled by replacing a portion of, particularly, the high melting metal component with an inert material or with a lower cost conductive material. Particularly preferred fillers for use in place of the high melting point metal are non-metals such as ceramics with melting points >300° C. and glasses or high temperature polymers with glass transition temperatures (T_(g))>200° C. An example would be thermosetting polymers such as polyimide. Two particular advantages of replacing the high melting point metal with one of these non-metals is that the active low melting point metal of the TLPS will not be consumed by diffusion during the TLPS bond formation. The second advantage of inert fillers when selected from a family of glasses having low melting points is that the glass within the mixture of the TLPS paste or preform will create a bond with the exposed glass frit of the non-terminated and exposed ceramic body of, for example, an MLCC. The non-metals can also be coated with the low melting point metal by methods such a spraying or plating.

Sintered metal interconnects of silver as well as nano-silver and nano-copper can also be used to form HTCA interconnects. The resulting interconnect can be formed using a low temperature sintering process but the bond formed has the high melting point of the associated with the metal, in the case of silver 960° C. However, these processes often require elevated pressures for prolonged times in batch operation that can limit throughput compared CuSn TLPS. Also, nano-sized metals can be prohibitively expensive.

Diffusion soldering can also be used as a joining method to form the HTCA interconnect. This combines features of conventional soldering and diffusion bonding processes. The process relies on reaction between a thin layer of molten solder and metal on the components to form one or more intermetallic phases that are solid at the joining temperature. Since a low melting point material, solder reacts with a higher melting point metal this may also be considered in the broader definition of TLPS.

Direct copper bonding can also be used as the HTCA but this is a high temperature diffusion process primarily used in die attach so could be detrimental to some components.

Methods to adhere an external termination to a solder pad or adjacent external termination can comprise coating two mating surfaces one with a high melting point metal and its mating surface with a low melting point metal. The coating process may consist of vapor deposition or plating. A second method is to sandwich a preform film made from a low melting point metal or an alloy of two or more low melting point metals between two planar surfaces coated with a high melting point metal. A third method is to create a paste consisting of particles of a high melting point metal such as copper and then adding particles of two alloyed low melting point metals and mixed into a dual purpose liquid that cleans the surfaces to be bonded and also serves as the liquid ingredient to the metal particles to form a paste mixture.

If full diffusion of the two metals is not complete in the stated cycle time and the maximum secondary reflow temperature is not reached, the joint can be subjected to a second heating process. In this case the joint, or assembly, can be subjected to a temperature higher than that of the low melting point material and held for a period of time from 15 minutes up to 2 hours. The time and temperature can be varied to provide a desirable secondary reflow temperature as dictated by secondary assembly processes or final environmental application requirements. In the case of the indium/silver TLPS, secondary melt temperatures in excess of 600° C. can be achieved.

In addition to applying a paste to form a TLPS alloy joint between suitable surfaces this can also be achieved with a preform. In its simplest manifestation the preform can be a thin foil of the low temperature TLPS component. Alternatively, the preform can be produced by casting and drying the paste to remove the solvent. The resulting solid preform can be placed between the surfaces to be bonded. In this case it may be necessary to add a suitable binder to the paste for additional strength after drying. In all these cases the preform should be malleable such that it can conform to the surfaces to be bonded.

An HTCA can be an interconnect comprising a single metal, such as indium, contained within a paste which can be used to form a bond to a surface coated with a high melting point metal, such as silver. The diffusion of the indium into silver allows a lower temperature transient liquid phase to form that subsequently reacts to achieve a higher temperature bond. Achieving a high rate of diffusion in the lower melting point paste is critical to this bond formation. In order to achieve the desired properties in the final joint, such as reduced voids and a homogeneous phase the addition of other metals to the paste may be desirable. However, it is critical to retain the high diffusivity of the low melting point material. For this reason if one or more metals are required in addition to the low melting point metal it is preferred that these be incorporated by coating the metal powders prior to forming the paste. Coating the lowest melting point metal onto the higher melting point metal is preferred to retain an active surface. Coatings also have the desired effect of reducing the diffusion lengths between the different metallic elements of the paste allowing preferred phases to be more readily formed as opposed to a simple mixing of one or more additional metal powders to the single metal paste.

Conductive adhesives as HTCA's are typically cross linking polymers filled with silver or gold particles that cure or cross link within a specified temperature range, generally 150° C., to form a mechanical bond to the materials to be joined. Their conductivity is created by the metal particles making intimate contact with one another, within the confines of the polymer matrix, to form an electrically conductive path from one particle to another. Because the binder is organic in nature, they have relatively low temperature capabilities, normally in the range of about 150° C. to about 300° C. Conductive epoxies, once cured, cannot be reworked. Unlike TLPS bonds, exposure to high heat or corrosive environments may decompose the polymeric bonds and oxidize the metal particles degrading the electrical properties. Both the electrical and mechanical performance of the interconnect can be compromised resulting in increased ESR and decreased mechanical strength.

Polymer solders HTCA's may comprise conventional solder systems based on Pb/Sn alloy systems or lead free systems, such as Sn/Sb, which are combined with crosslinking polymers which serve as cleaning agents. The cross-linked polymers also have the ability to form a cross-linked polymer bond, such as an epoxy bond, that forms during the melting phase of the metals thereby forming a solder alloy and a mechanical polymeric bond. An advantage of polymer solders is that the polymeric bond provides additional mechanical bond strength at temperatures above the melting point of the solder, thus giving the solder joint a higher operating temperature in the range of about 5 to 80° C. above the melting point of the solder. Polymer solders combine current solder alloys with a cross linking polymer within the same paste to provide both a metallurgical bond and a mechanical bond when cured, such as by heating, to provide additional solder joint strength at elevated temperatures. However, the upper temperature limits and joint strength has been increased, just by the physical properties of the materials. A practical limit of 300° C. remains whereas the bonds created by TLPS can achieve higher temperatures.

In many applications a high degree of porosity may be acceptable. However, in harsh environments, such a high humidity or in circuit board mounting processes, high porosity is not desirable since water or other chemicals may penetrate through the bond which may cause the bond to fail. A preferred embodiment of this invention is therefore to form a low porosity termination within the transient liquid phase sintering joint using a thermo-compression bonding process. This process has the added advantage of using a low process time of 15 to 30 seconds at a temperature in the range of 225° C. to 300° C. in a single step making it suitable for automation. Robust joints can be created for the application of attaching external leads to electronic elements, when leads are used, with a one-step low temperature process in less than 30 seconds and in combination with thermo-compression bonding.

Thermo compression bonding is also a preferred processing method when using polymer solder because it assists in the formation of a high-density metallurgical bond between the contacting surfaces. The advantages of thermo-compression include a more robust bond with respect to secondary attachment processes and attachments with higher strength are achieved. A compressive force of 0.5 to 4.5 Kilograms/cm² (7.1 to 64 psi) and more preferably 0.6 to 0.8 Kilograms/cm 2 (8.5 to 11 psi) is sufficient for demonstration of the thermo-compression teachings herein. About 0.63 Kilograms/cm2 (9 psi) is a particularly suitable pressure for demonstration of the teachings.

It is highly desirable to create a joint with minimum porosity that exhibits the following characteristics: strong mechanical strength in excess of 5 Lbs./inch for Pull Peel test, Tensile, and Shear high electrical conductivity, low initial process temperature in the range of 150° C. to 225° C., a secondary reflow temperature in excess of 300° C. or higher, between non-uniform surfaces making intimate contact or having gaps up to 0.015 inches.

High temperature insulating adhesives can be a thermal or moisture set adhesives, UV cure adhesives or pressure sensitive adhesives. Particularly preferred high temperature insulating adhesives include epoxy resins, phenolic formaldehyde resins, phenolic melamine formaldehyde resins, phenolic neoprene, resorcinol formaldehydes, polyesters, polyimides, cyanoacrylates, acrylics, styrene block copolymers, styrene butadiene copolymers, polyurethanes, polyarylenes, polysulfides, polyamides, silicones and waxes etc. The HTIA may be selected to form a bond at the same time as the HTCA or in some circumstances, it may be preferable to provide a separate bonding process. The HTIA bonding processes may be achieved by heating, UV curing, moisture curing or hot melt deposition. Additionally, the HTIA may contain inert fillers of sufficient size and dielectric properties to ensure minimal dielectric spacing between adjacent components as required by the circuit/stack design and service conditions.

The material of construction for the substrate is not particularly limited herein with standard printed circuit board (PCB) materials being suitable for use. Laminates, fiber reinforced resins, ceramic filled resins, specialty materials and flexible substrates are particularly suitable. Flame Retardant (FR) laminates are particularly suitable as an interposer material and especially FR-1, FR-2, FR-3, FR-4, FR-5 or FR-6. FR-2 is a phenolic paper, phenolic cotton paper or paper impregnated with phenol formaldehyde resin. FR-4 is particularly preferred which is a woven fiberglass cloth impregnated with epoxy resin. Composite epoxy materials (CEM) are suitable and particularly CEM-1, CEM-2, CEM-3, CEM-4 or CEM-5 each of which comprise reinforcement such as a cotton paper, non-woven glass or woven glass in epoxy. Glass substrates (G) are widely used such as G-5, G-7, G-9, G-10, G-11 and others with G-10 and G-11 being most preferred each of which is a woven glass in epoxy. Polytetrafluoroethylene (PTFE), which can be ceramic filled, or fiberglass reinforced such as in RF-35, is a particularly suitable substrate. Electronic grade ceramic materials such as polyether ether ketone (PEEK), alumina or yttria stabilized zirconia are available with 96% Al₂O₃ and 99.6% Al₂O₃ being readily available commercially. Bismaleimide-Triazine (BT) epoxy is a particularly suitable substrate material. Flexible substrates are typically a polyimide such as a polyimide foil available commercially as Kapton or UPILEX or a polyimide-fluoropolymer composite commercially available as Pyrelux. Ferrous alloys are also used such as Alloy 42, Invar, Kovar or non-ferrous materials such as Cu, Phosphor Bronze or BeCu.

The package, or portions of the package, can be over-molded by a non-conductive polymer or resin. The material used for over-molding is not particularly limited herein. Over-molding can be done to isolate the package, or components therein, from electrical interaction with other elements of a circuit or to protect the package, or components therein, from environmental variations. Over-molding can also be beneficial for labeling and for use with pick-and-place equipment since the over-molding can be applied with specific geometry identifiable by optical or mechanical equipment. Additionally, the package can be mechanically encapsulated in a case, shell or other assembly for use as a plug in electrical circuit or assembly utilizing commercially available electrical connections attached to the package via extant assembly methodologies.

The invention has been described with reference to the preferred embodiments without limit thereto. Additional embodiments and improvements may be realized which are not specifically set forth herein but which are within the scope of the invention as more specifically set forth in the claims appended hereto. 

1-72. (canceled)
 73. A method for forming a high density multi-component package comprising: providing at least two electronic components wherein each electronic component of said electronic components comprises a first external termination and a second external termination; forming a stack of adjacent said electronic components with at least one; attaching adjacent said first external terminations with a first adhesive there between; attaching said adjacent electronic components with a second adhesive there between; and wherein said adjacent electronic components are connected serially.
 74. The method of forming a high density multi-component package of claim 73 wherein said high temperature conductive adhesive and a high temperature insulating adhesive are bonded to the components in the same process.
 75. The method of forming a high density multi-component package of claim 73 wherein said high temperature conductive adhesive and a high temperature insulating adhesive are bonded to the components in separate processes.
 76. The method for forming a high density multi-component package of claim 73 wherein said second adhesive is said high temperature insulating adhesive and said second adhesive is between adjacent second external terminations.
 77. The method for forming a high density multi-component package of claim 73 further comprising a spacer between adjacent second external terminations.
 78. The method for forming a high density multi-component package of claim 77 wherein said spacer is selected from an air gap and a non-conducting material.
 79. The method for forming a high density multi-component package of claim 73 further comprising a secondary adhesive.
 80. The method for forming a high density multi-component package of claim 73 wherein each said electronic component is independently selected from the group consisting of capacitor, resistor, varistor, inductor, diode, fuse, overvoltage discharge device, sensor, switch, electrostatic discharge suppressor, semiconductor and integrated circuit.
 81. The method for forming a high density multi-component package of claim 80 wherein said capacitor an MLCC.
 82. The method for forming a high density multi-component package of claim 81 wherein said electronic component is selected from the group consisting of MLCC, resistor, varistor, inductor, diode, fuse, overvoltage discharge device, sensor, switch and electrostatic discharge suppressor.
 83. The method for forming a high density multi-component package of claim 82 wherein at least one said electronic component is an MLCC.
 84. The method for forming a high density multi-component package of claim 82 wherein said diode is a light emitting diode.
 85. The method for forming a high density multi-component package of claim 73 wherein all electronic components are serially connected.
 86. The method for forming a high density multi-component package of claim 73 wherein at least two additional electronic components are electrically connected in parallel.
 87. The method for forming a high density multi-component package of claim 73 comprising at least two stacks wherein a secondary electrical component spans said stacks.
 88. The method for forming a high density multi-component package of claim 87 wherein said secondary electrical component is selected from the group consisting of interposer, capacitor, resistor, varistor, inductor, diode, fuse, overvoltage discharge device, sensor, switch, electrostatic discharge suppressor, semiconductor and integrated circuit.
 89. The method for forming a high density multi-component package of claim 87 wherein said secondary electrical component is in electrical parallel with at least two said electronic components.
 90. The method for forming a high density multi-component package of claim 73 wherein said high temperature conductive adhesive is selected from the group consisting of solder, conductive adhesive, polymer solder and transient liquid phase sintering adhesive.
 91. The method for forming a high density multi-component package of claim 90 wherein said liquid phase sintering adhesive comprises a high melting point metal and a low melting point metal.
 92. The method for forming a high density multi-component package of claim 91 wherein said low melting point metal is selected from the group consisting of indium, tin, lead, antimony, bismuth, cadmium, zinc, gallium, tellurium, mercury, thallium, selenium, or polonium.
 93. The method for forming a high density multi-component package of claim 91 wherein said high melting point metal is selected from the group consisting of silver, copper, aluminum, gold, platinum, palladium, beryllium, rhodium, nickel, cobalt, iron and molybdenum.
 94. The method for forming a high density multi-component package of claim 91 wherein said transient liquid phase sintering adhesive comprises tin and copper or indium and silver.
 95. The method for forming a high density multi-component package of claim 73 wherein at least one said external termination comprises a metal selected from the group consisting of silver, tin, gold, copper, platinum, palladium and nickel.
 96. The method for forming a high density multi-component package of claim 73 wherein said high temperature insulating adhesive is selected from epoxy resins, phenolic formaldehyde resins, phenolic melamine formaldehyde resins, phenolic neoprene, resorcinol formaldehydes, polyesters, polyimides, cyanoacrylates, acrylics, styrene block copolymers, styrene butadiene copolymers, polyarylenes, polyurethanes, polysulfides, polyamides, silicones and waxes.
 97. The method for forming a high density multi-component package of claim 73 wherein said high density multi-component package is selected from the group consisting of a Pi filter, a T filter and an LC filter.
 98. The method for forming a high density multi-component package of claim 73 further comprising a substrate.
 99. The method for forming a high density multi-component package of claim 98 wherein said substrate comprises at least two circuit traces.
 100. The method for forming a high density multi-component package of claim 99 wherein said substrate comprises at least three circuit traces.
 101. The method for forming a high density multi-component package of claim 73 further comprising a flexible circuit.
 102. The method for forming a high density multi-component package of claim 73 further comprising overmolding. 103-112. (canceled)
 113. The method for forming a high density multi-component package of claim 73 wherein said first adhesive and said second adhesive are independently selected from the group consisting of a high temperature conductive adhesive and a high temperature insulating adhesive. 